To export a path from AI (CS5) do the following:
See also http://creativedroplets.com/transparent-png-with-illustrator/
Select the path(s) you want to export
Copy and paste it somewhere if necessary
Draw an artboard somewhere with the artboard tool
In the artboard presets select fit to artwork
Now export as png and check the box ‘use artboards’
Select your artboard
Select the correct resolution (if the resolution is different from the AI source, the png size will change accordingly)